Chemistry

الاثنين، 9 أبريل 2012

Chemical substance

In chemistry, a chemical substance is a form of matter that has constant chemical composition and characteristic properties.[1] It cannot be separated into components by physical separation methods, i.e. without breaking chemical bonds. They can be solids, liquids or gases.

Chemical substances are often called 'pure' to set them apart from mixtures. A common example of a chemical substance is pure water; it has the same properties and the same ratio of hydrogen to oxygen whether it is isolated from a river or made in a laboratory. Other chemical substances commonly encountered in pure form are diamond (carbon), gold, table salt (sodium chloride) and refined sugar (sucrose). However, simple or seemingly pure substances found in nature can in fact be mixtures of chemical substances. For example, tap water may contain small amounts of dissolved sodium chloride and compounds containing iron, calcium and many other chemical substances.

Chemical substances exist as solids, liquids, gases, or plasma and may change between these phases of matter with changes in temperature or pressure. Chemical reactions convert one chemical substance into another.

Forms of energy, such as light and heat, are not considered to be matter, and thus they are not "substances" in this regard.

Definition

Colors of a single chemical (Nile red) in different solvents, under visible and UV light.
Chemical substances (also called pure substances) are often defined as "any material with a definite chemical composition" in most introductory general chemistry textbooks.[2] According to this definition a chemical substance can either be a pure chemical element or a pure chemical compound. But, there are exceptions to this definition; a pure substance can also be defined as a form of matter that has both definite composition and distinct properties.[3] The chemical substance index published by CAS also includes several alloys of uncertain composition.[4] Non-stoichiometric compounds are a special case (in inorganic chemistry) that violates the law of constant composition, and for them, it is sometimes difficult to draw the line between a mixture and a compound, as in the case of palladium hydride. Broader definitions of chemicals or chemical substances can be found, for example: "the term 'chemical substance' means any organic or inorganic substance of a particular molecular identity, including – (i) any combination of such substances occurring in whole or in part as a result of a chemical reaction or occurring in nature"[5]
In geology, substances of uniform composition are called minerals, while physical mixtures (aggregates) of several minerals (different substances) are defined as rocks. Many minerals, however, mutually dissolve into solid solutions, such that a single rock is a uniform substance despite being a 'mixture'. Feldspars are a common example: anorthoclase is an alkali aluminum silicate, where the alkali metal is interchangeably either sodium or potassium.

History

The concept of a "chemical substance" became firmly established in the late eighteenth century after work by the chemist Joseph Proust on the composition of some pure chemical compounds such as basic copper carbonate.[6] He deduced that, "All samples of a compound have the same composition; that is, all samples have the same proportions, by mass, of the elements present in the compound." This is now known as the law of constant composition.[7] Later with the advancement of methods for chemical synthesis particularly in the realm of organic chemistry; the discovery of many more chemical elements and new techniques in the realm of analytical chemistry used for isolation and purification of elements and compounds from chemicals that led to the establishment of modern chemistry, the concept was defined as is found in most chemistry textbooks. However, there are some controversies regarding this definition mainly because the large number of chemical substances reported in chemistry literature need to be indexed.

Chemical elements

Native sulfur crystals. Sulfur occurs naturally as elemental sulfur, in sulfide and sulfate minerals and in hydrogen sulfide.
Main article: Chemical element
See also: List of elements by name
An element is a chemical substance that is made up of a particular kind of atoms and hence cannot be broken down or transformed by a chemical reaction into a different element, though it can be transmutated into another element through a nuclear reaction. This is so, because all of the atoms in a sample of an element have the same number of protons, though they may be different isotopes, with differing numbers of neutrons.
There are about 120 known elements, about 80 of which are stable – that is, they do not change by radioactive decay into other elements. However, the number of chemical substances that are elements can be more than 120, because some elements can occur as more than a single chemical substance (allotropes). For instance, oxygen exists as both diatomic oxygen (O2) and ozone (O3). The majority of elements are classified as metals. These are elements with a characteristic lustre such as iron, copper, and gold. Metals typically conduct electricity and heat well, and they are malleable and ductile.[8] Around a dozen elements,[9] such as carbon, nitrogen, and oxygen, are classified as non-metals. Non-metals lack the metallic properties described above, they also have a high electronegativity and a tendency to form negative ions. Certain elements such as silicon sometimes resemble metals and sometimes

Chemical compounds

Main article: Chemical compound
See also: List of organic compounds and List of inorganic compounds
A pure chemical compound is a chemical substance that is composed of a particular set of molecules or ions. Two or more elements combined into one substance through a chemical reaction form a chemical compound. All compounds are substances, but not all substances are compounds.
A chemical compound can be either atoms bonded together in molecules or crystals in which atoms, molecules or ions form a crystalline lattice. Compounds based primarily on carbon and hydrogen atoms are called organic compounds, and all others are called inorganic compounds. Compounds containing bonds between carbon and a metal are called organometallic compounds.
Compounds in which components share electrons are known as covalent compounds. Compounds consisting of oppositely charged ions are known as ionic compounds, or salts.
In organic chemistry, there can be more than one chemical compound with the same composition and molecular weight. Generally, these are called isomers. Isomers usually have substantially different chemical properties, may be isolated and do not spontaneously convert to each other. A common example is glucose vs. fructose. The former is an aldehyde, the latter is a ketone. Their interconversion requires either enzymatic or acid-base catalysis. However, there are also tautomers, where isomerization occurs spontaneously, such that a pure substance cannot be isolated into its tautomers. A common example is glucose, which has open-chain and ring forms. One cannot manufacture pure open-chain glucose because glucose spontaneously cyclizes to the hemiacetal form.

Chemical compound

A chemical compound is a pure chemical substance consisting of two or more different chemical elements[1][2][3] that can be separated into simpler substances by chemical reactions.[4] Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms[3] that are held together in a defined spatial arrangement by chemical bonds. Chemical compounds can be molecular compounds held together by covalent bonds, salts held together by ionic bonds, intermetallic compounds held together by metallic bonds, or complexes held together by coordinate covalent bonds. Pure chemical elements are not considered chemical compounds, even if they consist of molecules which contain only multiple atoms of a single element (such as H2, S8, etc.),[5] which are called diatomic molecules or polyatomic molecules.

Wider definitions

There are exceptions to the definition above, and large amounts of the solid chemical matter familiar on Earth do not have simple formulas. Certain crystalline compounds are called "non-stoichiometric" because they vary in composition due to either the presence of foreign elements trapped within the crystal structure or a deficit or excess of the constituent elements. Such non-stoichiometric chemical compounds form most of the crust and mantle of the Earth.
Other compounds regarded as chemically identical may have varying amounts of heavy or light isotopes of the constituent elements, which will make the ratio of elements by mass vary slightly.

Elementary concepts

Characteristic properties of compounds:
Elements in a compound are present in a definite proportion
Example- 2 atoms of hydrogen + 1 atom of oxygen becomes 1 molecule of compound-water.
Compounds have a definite set of properties
Elements comprising a compound do not retain their original properties.
Example: hydrogen (element, which is combustible and non-supporter of combustion) + oxygen (element, which is non-combustible and supporter of combustion) becomes water (compound, which is non-combustible and non-supporter of combustion)
Valency is the number of hydrogen atoms which can combine with one atom of the element forming a compound.

Compounds compared to mixtures

The physical and chemical properties of compounds are different from those of their constituent elements. This is one of the main criteria for distinguishing a compound from a mixture of elements or other substances because a mixture's properties are generally closely related to and dependent on the properties of its constituents. Another criterion for distinguishing a compound from a mixture is that the constituents of a mixture can usually be separated by simple, mechanical means such as filtering, evaporation, or use of a magnetic force, but the components of a compound can only be separated by a chemical reaction. Conversely, mixtures can be created by mechanical means alone, but a compound can only be created (either from elements or from other compounds, or a combination of the two) by a chemical reaction.
Some mixtures are so intimately combined that they have some properties similar to compounds and may easily be mistaken for compounds. One example is alloys. Alloys are made mechanically, most commonly by heating the constituent metals to a liquid state, mixing them thoroughly, and then cooling the mixture quickly so that the constituents are trapped in the base metal. Other examples of compound-like mixtures include intermetallic compounds and solutions of alkali metals in a liquid form of ammonia.

Chemical element

A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. Familiar examples of elements include carbon, oxygen, aluminium, iron, copper, gold, mercury, and lead.

As of November 2011, 118 elements have been identified, the latest being ununseptium in 2010.[1] Of the 118 known elements, only the first 98 are known to occur naturally on Earth. Of these, 80 are stable, while the others are radioactive, decaying into lighter elements over various timescales from fractions of a second to billions of years. Those elements that do not occur naturally on Earth have been produced artificially as the synthetic products of man-made nuclear reactions.

Hydrogen and helium are by far the most abundant elements in the universe. However, iron is the most abundant element (by mass) making up the Earth, and oxygen is the most common element in the Earth's crust.[2] Although all known chemical matter is composed of these elements, chemical matter itself constitutes only about 15% of the matter in the universe. The remainder is dark matter, a mysterious substance which is not composed of chemical elements since it lacks protons, neutrons or electrons.[3]

The chemical elements are thought to have been produced by various cosmic processes, including hydrogen, helium (and smaller amounts of lithium, beryllium and boron) created during the Big Bang and cosmic-ray spallation. Production of heavier elements, from carbon to the very heaviest elements, proceeds by stellar nucleosynthesis, and these were made available for later solar system and planetary formation by supernovae, which blast these elements into space.[4] The high abundance of oxygen, silicon, and iron on Earth reflect their common production in such stars, after the lighter gaseous elements and their compounds have been subtracted. While most elements are generally viewed as stable, a small amount of natural transformation of one element to another also occurs in the present time, through decay of radioactive elements as well as other natural nuclear processes.

Relatively pure samples of isolated elements are uncommon in nature. While all of the 98 naturally occurring elements have been identified in mineral samples from the Earth's crust, only a small minority of elements are found as recognizable, relative pure minerals. Among the more common of such "native elements" are copper, silver, gold, carbon (as coal, graphite, or diamonds), sulfur, and mercury. All but a few of the most inert elements, such as noble gases and noble metals, are usually found on Earth in chemically combined form, as chemical compounds. While about 32 of the chemical elements occur on Earth in native uncombined form, most of these occur as mixtures. For example, atmospheric air is primarily a mixture of nitrogen, oxygen, and argon, and native solid elements occur in alloys, such as that of iron and nickel.

When two distinct elements are chemically combined, with the atoms held together by chemical bonds, the result is termed a chemical compound. Two thirds of the chemical elements occur on Earth only as compounds, and in the remaining third, often the compound forms of the element are most common.[citation needed] Chemical compounds may be composed of elements combined in exact whole-number ratios of atoms, as in water, table salt, and minerals as quartz, calcite, and some ores. However, chemical bonding of many types of elements results in crystalline solids and metallic alloys for which exact chemical formulas do not exist.

The history of discovery and use of the elements began with primitive human societies that found native elements like copper and gold, and extracted (smelted) iron and a few other metals from their ores. Alchemists and chemists subsequently identified many more, with nearly all of the naturally-occurring elements known by 1900. The properties of the chemical elements are often summarized using the periodic table that organizes the elements by increasing atomic number into rows ("periods") in which the columns ("groups") share recurring ("periodic") physical and chemical properties. Either in its pure forms, or in various chemical compounds or mixtures, almost every element has at least one important human use. Save for short half-lived radioactive elements, all of the elements are available industrially, most to high degrees of purity.

Around two dozen of the elements are essential to various kinds of biological life. Most rare elements on Earth are not needed by life (exceptions being selenium and iodine), while a few quite common ones (aluminium and titanium) are not used. Most organisms share element needs, with a few differences. For example, ocean algae use bromine but land plants and animals seem to need none, and all animals require sodium, but some plants do not. Just six elements—carbon, hydrogen, nitrogen, oxygen, calcium, and phosphorus—make up almost 99% of the mass of a human body (see composition of the human body for a complete list). In addition to the six major elements that compose most of the human body, humans require consumption of at least a dozen more elements in the form of certain chemical compounds.

Atom

The atom is a basic unit of matter that consists of a dense central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons (except in the case of hydrogen-1, which is the only stable nuclide with no neutrons). The electrons of an atom are bound to the nucleus by the electromagnetic force. Likewise, a group of atoms can remain bound to each other, forming a molecule. An atom containing an equal number of protons and electrons is electrically neutral, otherwise it has a positive charge if there are fewer electrons (electron deficiency) or negative charge if there are more electrons (electron excess). A positively or negatively charged atom is known as an ion. An atom is classified according to the number of protons and neutrons in its nucleus: the number of protons determines the chemical element, and the number of neutrons determines the isotope of the element.[1]

The name atom comes from the Greek ἄτομος (atomos, "indivisible") from ἀ- (a-, "not") and τέμνω (temnō, "I cut"),[2] which means uncuttable, or indivisible, something that cannot be divided further.[3] The concept of an atom as an indivisible component of matter was first proposed by early Indian and Greek philosophers. In the 17th and 18th centuries, chemists provided a physical basis for this idea by showing that certain substances could not be further broken down by chemical methods. During the late 19th and early 20th centuries, physicists discovered subatomic components and structure inside the atom, thereby demonstrating that the 'atom' was divisible. The principles of quantum mechanics were used to successfully model the atom.[4][5]

Atoms are minuscule objects with proportionately tiny masses. Atoms can only be observed individually using special instruments such as the scanning tunneling microscope. Over 99.94% of an atom's mass is concentrated in the nucleus,[note 1] with protons and neutrons having roughly equal mass. Each element has at least one isotope with unstable nuclei that can undergo radioactive decay. This can result in a transmutation that changes the number of protons or neutrons in a nucleus.[6] Electrons that are bound to atoms possess a set of stable energy levels, or orbitals, and can undergo transitions between them by absorbing or emitting photons that match the energy differences between the levels. The electrons determine the chemical properties of an element, and strongly influence an atom's magnetic properties.

Etymology

he word chemistry comes from the word alchemy, an earlier set of practices that encompassed elements of chemistry, metallurgy, philosophy, astrology, astronomy, mysticism and medicine; it is commonly thought of as the quest to turn lead or another common starting material into gold.[26] The word alchemy in turn is derived from the Arabic word al-kīmīā (الكيمياء), meaning alchemy. The Arabic term is borrowed from the Greek χημία or χημεία.[27][28] This may have Egyptian origins. Many believe that al-kīmīā is derived from χημία, which is in turn derived from the word Chemi or Kimi, which is the ancient name of Egypt in Egyptian.[27] Alternately, al-kīmīā may be derived from χημεία, meaning "cast together".[29]

An alchemist was called a 'chemist' in popular speech, and later the suffix "-ry" was added to this to describe the art of the chemist as "chemistry".

Definitions

In retrospect, the definition of chemistry has changed over time, as new discoveries and theories add to the functionality of the science. Shown below are some of the standard definitions used by various noted chemists:

Alchemy (330) – the study of the composition of waters, movement, growth, embodying, disembodying, drawing the spirits from bodies and bonding the spirits within bodies (Zosimos).[30]

Chymistry (1661) – the subject of the material principles of mixed bodies (Boyle).[31]

Chymistry (1663) – a scientific art, by which one learns to dissolve bodies, and draw from them the different substances on their composition, and how to unite them again, and exalt them to a higher perfection (Glaser).[32]

Chemistry (1730) – the art of resolving mixed, compound, or aggregate bodies into their principles; and of composing such bodies from those principles (Stahl).[33]

Chemistry (1837) – the science concerned with the laws and effects of molecular forces (Dumas).[34]

Chemistry (1947) – the science of substances: their structure, their properties, and the reactions that change them into other substances (Pauling).[35]

Chemistry (1998) – the study of matter and the changes it undergoes (Chang).[36]

الجمعة، 6 أبريل 2012

Uranium

Uranium is a silvery-white metallic chemical element in the actinide series of the periodic table, with atomic number 92. It is assigned the chemical symbol U. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. The uranium nucleus binds between 141 and 146 neutrons, establishing six isotopes (U-233 through U-238), the most common of which are uranium-238 (146 neutrons) and uranium-235 (143 neutrons). All isotopes are unstable and uranium is weakly radioactive. Uranium has the second highest atomic weight of the naturally occurring elements, lighter only than plutonium-244.[3] Its density is about 70% higher than that of lead, but not as dense as gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite.

In nature, uranium is found as uranium-238 (99.2739–99.2752%), uranium-235 (0.7198–0.7202%), and a very small amount of uranium-234 (0.0050–0.0059%).[4] Uranium decays slowly by emitting an alpha particle. The half-life of uranium-238 is about 4.47 billion years and that of uranium-235 is 704 million years,[5] making them useful in dating the age of the Earth.

Many contemporary uses of uranium exploit its unique nuclear properties. Uranium-235 has the distinction of being the only naturally occurring fissile isotope. Uranium-238 is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239 in a nuclear reactor. Another fissile isotope, uranium-233, can be produced from natural thorium and is also important in nuclear technology. While uranium-238 has a small probability for spontaneous fission or even induced fission with fast neutrons, uranium-235 and to a lesser degree uranium-233 have a much higher fission cross-section for slow neutrons. In sufficient concentration, these isotopes maintain a sustained nuclear chain reaction. This generates the heat in nuclear power reactors, and produces the fissile material for nuclear weapons. Depleted uranium (238U) is used in kinetic energy penetrators and armor plating.[6]

Uranium is used as a colorant in uranium glass, producing orange-red to lemon yellow hues. It was also used for tinting and shading in early photography. The 1789 discovery of uranium in the mineral pitchblende is credited to Martin Heinrich Klaproth, who named the new element after the planet Uranus. Eugène-Melchior Péligot was the first person to isolate the metal and its radioactive properties were discovered in 1896 by Antoine Becquerel. Research by Enrico Fermi and others starting in 1934 led to its use as a fuel in the nuclear power industry and in Little Boy, the first nuclear weapon used in war. An ensuing arms race during the Cold War between the United States and the Soviet Union produced tens of thousands of nuclear weapons that used uranium metal and uranium-derived plutonium-239. The security of those weapons and their fissile material following the breakup of the Soviet Union in 1991 is an ongoing concern for public health and safety.[7] See Nuclear proliferation.